Filippo Mangolini

 

Phone Number: 215-898-4591
Email: mfilippo@seas.upenn.edu
Office: 112 Towne

Education

Ph.D., Materials Science (2011), Laboratory for Surface Science and Technology (LSST), Department of Materials of the Swiss Federal Institute of Technology , ETH Zurich, Zurich, Switzerland

Thesis: “Reactivity of Environmentally Compatible Lubricant Additives: an In Situ and Ex Situ Investigation”

Adviser: Prof. Dr. Nicholas D. Spencer, Prof. Antonella Rossi

 

Master Degree in Materials Engineering, Politecnico of Milan, Milan, Italy

Bachelor Degree in Materials Engineering, Politecnico of Milan, Milan, Italy

 

Research Interests

Currently my research focuses on:

  1. the development of a new in situ tribological method, based on environmental X-ray photoelectron spectroscopy (E-XPS);
  2. the development of a fundamental understanding of the influence of the environment on the thermal degradation pathway, kinetics and energetics of silicon oxide-doped diamond-like carbon (SiOx-DLC);
  3. studying the scientific foundation of the influence of the environment on the tribological performance of diamond and diamond-like carbon (DLC) solid lubricants as well as their derivatives (e.g., SiOx-DLC).

This research is supported by the Marie Curie International Outgoing Fellowship (IOF) for Career Development within the 7th European Community Framework Programme (under contract no. PIOF-GA-2012-328776), the National Science Foundation under Grant No. DMR-1107642, and the Advanced Storage Technology Consortium ASTC under Grant No. 2011-012.

 

Publications

Peer-Reviewed Journal Articles

  1. F. Streller, G. E. Wabiszewski, F. Mangolini, G. Feng, and R. W. Carpick, Tunable, Source-Controlled Formation of Platinum Silicides and Nanogaps from Thin Precursor Films, Advanced Materials Interfaces, 1(3), 1300120, 2014, http://dx.doi.org/10.1002/admi.201300120
  2. F. Mangolini, F. Rose, J. Hilbert, R.W. Carpick, Thermally Induced Evolution of Hydrogenated Amorphous Carbon, 103(16), 161605, 2013, http://dx.doi.org/10.1063/1.4826100
  3. F. Mangolini, J. Ahlund, G.E. Wabiszewski, V.P. Adiga, P. Egberts, F. Streller, K. Backlund, P.G. Karlsson, B. Wannberg, R.W. Carpick, Angle-Resolved X-Ray Photoelectron Spectroscopy: A New Laboratory Setup for Photoemission Studies at Pressures Up To 0.4 Torr, Review of Scientific Instruments, 83(9), 093112, 2012, http://dx.doi.org/10.1063/1.4754127
  4. T.R. Gordon, M. Cargnello, T. Paik, F. Mangolini, R.T. Weber, P. Fornasiero, C.B. Murray, Nonaqueous Synthesis of TiO2 Nanocrystals Using TiF4 to Engineer Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity, Journal of the American Chemical Society, 134(15), 6751-6761, 2012, http://dx.doi.org/10.1021/ja300823a
  5. M. Crobu, A. Rossi, F. Mangolini, N.D. Spencer, Chain-Length-Identification Strategy in Zinc Polyphosphate Glasses by means of XPS and ToF-SIMS, Analytical and Bioanalytical Chemistry, 403(5), 1415-1432, 2012, http://dx.doi.org/10.1007/s00216-012-5836-7
  6. F. Mangolini, A. Rossi, N.D. Spencer, Tribochemistry of Triphenyl Phosphorothionate (TPPT) by In Situ Attenuated Total Reflection (ATR/FT-IR) Tribometry, Journal of Physical Chemistry C, 116(9), 5614-5627, 2012, http://dx.doi.org/10.1021/jp209697a
  7. F. Mangolini, A. Rossi, N.D. Spencer, In Situ Attenuated Total Reflection (ATR/FT-IR) Tribometry: a Powerful Tool for Investigating Tribochemistry at the Lubricant-Substrate Interface, Tribology Letter, 45(1), 207-218, 2012, http://dx.doi.org/10.1007/s11249-011-9868-5
  8. F. Mangolini, A. Rossi, N.D. Spencer, Influence of Metallic and Oxidized Iron/steel on the Reactivity of Triphenyl Phosphorothionate in Oil Solution, Tribology International, 44(6) (Special issue on Advances in Boundary Lubrication and Boundary Surface Films), 670-683, 2011, http://dx.doi.org/10.1016/j.triboint.2010.02.009
  9. F. Mangolini, A. Rossi, N.D. Spencer, Chemical Reactivity of Triphenyl Phosphorothioante (TPPT) with Iron: an ATR/FT-IR and XPS Investigation, Journal of Physical Chemistry C, 115(4) (Part of the “Alfons Baiker Festschrift”), 1339-1354, 2011, http://dx.doi.org/10.1021/jp107617d
  10. F. Mangolini, A. Rossi, N.D. Spencer, Substituent effect on the Reactivity of Alkylated Triphenyl Phosphorothionates in Oil Solution, Tribology Letters, 40(3), 375-394, 2010, http://dx.doi.org/10.1007/s11249-010-9659-4
  11. M. Crobu, A. Rossi, F. Mangolini and N.D. Spencer, Tribochemistry of Bulk Zinc Metaphosphate Glasses, Tribology Letters, 39(2), 121-134, 2010, http://dx.doi.org/10.1007/s11249-010-9622-4
  12. F. Mangolini, A. Rossi, N.D. Spencer, Reactivity of Triphenyl Phosphorothionate in Oil Solution, Tribology Letters, 35(1), 32-43, 2009, http://dx.doi.org/10.1007/s11249-009-9429-3
  13. F. Mangolini, L. Magagnin and P.L. Cavallotti, Pulse Plating of Mn–Cu Alloys from a Sulfate Bath, Transactions of the Institute of Metal Finishing, 85 (1), 2007, http://dx.doi.org/10.1179/174591907X162477
  14. F. Mangolini, L. Magagnin and P.L. Cavallotti, Pulse Plating of Mn–Cu alloys on steel, Journal of the Electrochemical Society, 153 (9), C623–C628, 2006, http://dx.doi.org/10.1149/1.2216431

 

Contributed Book Chapters

  1. F. Mangolini, A.Rossi, Attenuated Total Reflection (ATR/FT-IR) Spectroscopy: a Powerful Tool for Investigating Polymer Surfaces and Interfaces, L. Sabbatini, Ed., De Gruyter, Berlin, Germany. June 2014

 

Non-Refereed Contributions

  1. J. Åhlund, F. Mangolini, R.W. Carpick, XPS on Carbon Films, VG Scienta, Application Note
  2. J. Hilbert, F. Mangolini, J.R. Lukes, R.W. Carpick, Experimental and Simulation-Based Investigation of the Thermal Stability of Silicon Oxide-Doped Diamond-Like Carbon, Tribology and Lubrication Technology, March 2014
  3. J. Åhlund, F. Mangolini, R.W. Carpick, AR-XPS at Environmental Conditions, VG Scienta, Application Note

 

Presentations

  1. F. Mangolini,  Fundamental Surface-Analytical Investigations in Tribology: The Challenges of Studying Phenomena at Sliding Interfaces (keynote lecture). Italian Chemical Society (SCI) XXV Congress, Cosenza, Italy. September 7th-12th, 2014
  2. J. Peng, A. Sergiienko, P.E. Stallworth, S.G. Greenbaum, F. Mangolini, R.W. Carpick, Multinuclear NMR and EPR Studies of SiOx-doped Diamond-Like Carbon (oral presentation). International Conference on Diamond and Carbon Materials, Madrid, Spain. September 7th-11th, 2014
  3. R.W. Carpick, T.D.B. Jacobs, N.N. Gosvami, J.A. Bares, F. Mangolini, A.R. Konicek, D.G. Yablon, Atomic-Scale Processes in Tribology Elucidated by In Situ Approaches (oral presentation). 41st Leeds-Lyon Symposium on Tribology, Leeds Trinity University, The University of Leeds, UK. September 2nd-5th, 2014
  4. F. Mangolini, J.B. McClimon, J. Hilbert, J.R. Lukes, R.W. Carpick, In Situ XPS and NEXAFS Investigation of the Thermally-Induced Structural Evolution of Advanced Amorphous Carbon-Based Surfaces (oral presentation). 248th American Chemical Society (ACS) National Meeting & Exposition, San Francisco, US. August 10th-14th, 2014
  5. M. Koshigan, F. Mangolini, J. Hilbert, J.B. McClimon, T. Le Mogne, R.W. Carpick, S. Bec, J. Fontaine, Do Silicon Oxide Doped (SiOx-DLC) films get help from the environment during sliding? (oral presentation). 248th American Chemical Society (ACS) National Meeting & Exposition, San Francisco, US. August 10th-14th, 2014
  6. N.N. Gosvami, J.A. Bares, F. Mangolini, A.R. Konicek, A.M. Schilowitz, D.G. Yablon, R.W. Carpick, In Situ Study of the Growth Mechanisms and Kinetics of ZDDP Anti-Wear Tribofilms in Nanoscale Single-Asperity Contacts (oral presentation). 248th American Chemical Society (ACS) National Meeting & Exposition, San Francisco, US. August 10th-14th, 2014
  7. R.W. Carpick, F. Mangolini, J. Hilbert, J.R. Lukes, Thermo-Oxidative Stability of SiOx-doped Diamond-Like Carbon Studied via Environmental XPS and AFM (oral presentation). Microscopy and Microanalysis, Hartford, US. August 3rd-7th, 2014
  8. J.B. McClimon, F. Mangolini, J. Hilbert, J.R. Lukes, R.W. Carpick, Thermally-Induced Evolution of Silicon Oxide-Doped Diamond-Like Carbon Surfaces (poster presentation). Gordon Research Conference – Tribology, Waltham, US. July 20th-25th, 2014
  9. K.D. Koshigan, F. Mangolini, B. Vacher, J. Hilbert, J.B. McClimon, T. Le Mogne, S. Bec, R.W. Carpick, J. Fontaine,On the Understanding of Silicon Oxide Doped Diamond-Like Carbon Films’ Friction Mechanisms and Their Dependence on Sliding Environment (poster presentation). Gordon Research Conference – Tribology, Waltham, US. July 20th-25th, 2014
  10. J. Hilbert, F. Mangolini, J.B. McClimon, J.R. Lukes, R.W. Carpick, Investigating the Thermally Stability of Silicon Oxide-Doped Diamond-Like Carbon (SiOx-DLC) through Experiments and Simulation (poster presentation). Gordon Research Conference – Tribology, Waltham, US. July 20th-25th, 2014
  11. N.N. Gosvami, J.A. Bares, F. Mangolini, A.R. Konicek, A.M. Schilowitz, D.G. Yablon, R.W. Carpick, Tribochemical Reactions in Single Asperity Contacts: Exploring Mechanisms of Antiwear Tribofilm Growth (poster presentation).Gordon Research Conference – Tribology, Waltham, US. July 20th-25th, 2014
  12. F. Mangolini, J. Hilbert, J.B. McClimon, J.R. Lukes, R.W. Carpick, Unraveling the Physical Pathways and Energetics of the Thermally-Induced Structural Evolution of Hydrogenated Amorphous Carbon Surfaces (oral presentation). American Chemical Society (ACS) 2014 Colloid & Surface Science Symposium, Philadelphia, US. June 22nd-25th, 2014
  13. F. Mangolini, M. Koshigan, J. Hilbert, J.R. Lukes, S. Bec, J. Fontaine, R.W. Carpick, Thermally-Induced Evolution of Silicon-Oxide Diamond-Like Carbon: Effect of Nanoscale Tribo-Mechanical Properties, Surface Structure, and Chemistry (oral presentation). Society of Tribologists and Lubrication Engineers (STLE) 69th Annual Meeting, Lake Buena Vista, Florida, US. May 18th-22nd, 2014
  14. R.W. Carpick, F. Streller, G.E. Wabiszewski, F. Mangolini, G. Feng, G. Piazza, Materials Challenges in NEMS Logic: Failure Mechanisms and Novel Materials Solutions (oral presentation). 2014 Materials Research Society (MRS) Spring Meeting & Exhibit, San Francisco, US. April 21st-25th, 2014
  15. F. Mangolini, F. Rose, J. Hilbert, J.R. Lukes, R.W. Carpick, Thermally-Induced Evolution of Hydrogenated Amorphous Carbon Surfaces (poster presentation), American Vacuum Society (AVS) 60th International Symposium & Exhibition, Long Beach, CA, US, October 27th-November 1st, 2013
  16. P. Nalam, E. Buck, F. Mangolini, R.J. Composto, R.W. Carpick, Nanocrystalline Diamond Atomic Force Microscope Probes with Strong Covalent Functionalization for Robust Nanopatterning (poster presentation), NanoDay@UPenn 2013, Philadelphia, PA, US, October 23rd, 2013
  17. F. Mangolini, J. Hilbert, J.R. Lukes, R.W. Carpick, Assessment of the Thermo-Oxidative Stability of Silicon Oxide-Doped Diamond-Like Carbon by In Situ Environmental X-Ray Photoelectron Spectroscopy (oral presentation), World Tribology Congress 2013, Turin, Italy, September 8-13th, 2013
  18. F. Mangolini, B.A. Krick, W.G. Sawyer, T.W. Scharf, J.A. Ohlhausen, S.V. Prasad, J. Hilbert, J. Fontaine, R.W. Carpick, Investigating the Tribochemistry of Silicon Oxide-Doped Diamond-Like Carbon: from Ultra-High Vacuum Systems to the International Space Station (oral presentation), 40th Leeds-Lyon Symposium on Tribology & Tribochemistry Forum 2013 (satellite forum of the World Tribology Congress WTC 2013), Lyon, France, September 4-6th, 2013
  19. J. Hilbert, F. Mangolini, J.R. Lukes, R.W. Carpick, Investigating the Thermally Stability of Silicon Oxide-Doped Diamond-Like Carbon (SiOx-DLC) through Experiments and Simulation (poster presentation). 68th STLE Annual Meeting & Exhibition, Detroit, US. May 5th-9th, 2013
  20. F. Mangolini, In Situ Attenuated Total Reflection Tribometry: a Powerful Tool for Investigating Tribochemistry at the Lubricant-Substrate Interface (invited lecture), ExxonMobil Friction and Wear Symposium, Princeton, US, April 8th, 2013
  21. F. Mangolini, F. Rose, J. Hilbert, R.W. Carpick, Assessment of the Thermal Stability of Hydrogenated Amorphous Carbon for Next-Generation Hard Disk Applications (oral presentation), Thermal Analysis Forum of the Delaware Valley: Application of Thermal Analysis in Research, ASTM International, West Conshohocken, US. March 14th, 2013
  22. T.R. Gordon, M. Cargnello, T. Paik, F. Mangolini, R.T. Weber, P. Fornasiero, C.B. Murray, Tailoring the Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity of TiO2 Nanocrystals Through Nonaqueous Synthesis (oral presentation). 244th ACS National Meeting & Exposition, Philadelphia, US. August 19th-23rd, 2012
  23. F. Mangolini, B.A. Krick, W.G. Sawyer, S.V. Prasad, J. Hilbert, R.W. Carpick, Performance of Silicon Oxide-Doped Diamond-Like Carbon (SiO-DLC) in Low Earth Orbit (LEO) (poster presentation), Gordon Research Conferences – Tribology, Waterville, US. July 8-13th, 2012
  24. F. Mangolini, A. Rossi, N.D. Spencer, Reactivity of an Ashless Anti-Wear Additive on Iron Surfaces: a Combined In Situ (ATR/FT-IR) and Ex Situ (XPS) Investigation (oral presentation), Advances in Lubrication: Linking Molecular, Meso, and Machine Scales, organized by the Engineering Conferences International (ECI), Puntarenas, Costa Rica. January 8-13th, 2012.
  25. R.W. Carpick, J. Fontaine, S. Bec, T. LeMogne, F. Mangolini, S.V. Prasad, Superlow Friction of Diamond-Like Nanocomposite (DLN) Coatings Under Oxygen and Hydrogen Ambient (oral presentation). 10th International Space Conference on Protection of Materials and Structures from the Space Environment (ICPMSE-10J), Nago, Japan. June 12th-17th, 2011
  26. A. Rossi, M. Crobu, F. Mangolini, N.D. Spencer, Practical Surface Analysis in a Complex Engineering Problem: the Challenge of Understanding the Tribochemistry of Anti-Wear Additives. XXII Convegno della Divisione di Chimica Analitica, organized by the Italian Chemical Society, Como, Italy. September 12th-16th, 2010
  27. A. Rossi, M. Crobu, F. Mangolini, N.D. Spencer, Analisi di Superficie Applicata a Complessi Problemi Ingegneristici: la Tribochimica degli Additivi Antiusura (oral presentation). Incontro di Spettroscopia Analitica (ISA) 2010, organized by the Italian Chemical Society, Rimini, Italy. June 16th-18th, 2010
  28. F. Mangolini, Non-contact (Optical) Profilometry (invited lecture), European Marie Curie International Training Network on Marine Biofouling (SEACOAT), ETH Zurich, Zurich, Switzerland, July 12-14th, 2010
  29. F. Mangolini, A. Rossi, N.D. Spencer, Growth of Thermal Films from an Environmentally Friendly Anti-wear Additive: a Combined In Situ (ATR/FT-IR) and Ex Situ (XPS) Analytical Study (poster presentation), Annual Meeting of the Swiss Working Group on Surfaces and Interface Science (SAOG), Fribourg, Switzerland, January 22nd, 2010
  30. F. Mangolini, A. Rossi, N.D. Spencer, Mechanical Stability of Thermal Films Formed on Bearing Steel in the Presence of Environmentally Friendly Additives: an XPS Analytical Study (poster presentation), World Tribology Congress WTC 2009, Kyoto, Japan. September 6-11th, 2009
  31. F. Mangolini, A. Rossi, N.D. Spencer, In situ Attenuated Total Reflection (ATR) Tribometry of Environmentally Friendly Antiwear Additives (oral presentation), Tribochemistry 2009 (satellite forum of the World Tribology Congress WTC 2009), Kyoto, Japan. September 2-4th, 2009
  32. F. Mangolini, A. Rossi, N.D. Spencer, Thermal Reactivity of Environmentally Friendly Antiwear Additives in Oil Solution (oral presentation), Advances in Boundary Lubrication and Boundary Surface Films, organized by the Engineering Conferences International (ECI), Seville, Spain. March 29th-April 3rd, 2009
  33. M. Crobu, F. Mangolini, A. Rossi, N.D. Spencer, Environmentally Compatible, Energy-Efficient Lubricants: an Analytical Study of the Tribochemistry of Anti-Wear Additives (poster presentation), Today, Tomorrow and Beyond (Materials Day), ETH Zurich, Zurich, Switzerland. March 19th, 2009
  34. F. Mangolini, A. Rossi, N.D. Spencer, Tribological Properties of Thermal Films Formed on Iron in the Presence of Environmentally Friendly Additives: an i-XPS Analytical Study (poster presentation), Gordon Research Conferences – Tribology, Waterville, US. July 6-11th, 2008
  35. F. Mangolini, A. Rossi, N.D. Spencer, Chemical Analysis by i-XPS of Thermal Films Formed on Iron in the Presence of an Environmentally Friendly Additive (poster presentation), Incontro di Spettroscopia Analitica (ISA) 2008, organized by the Italian Chemical Society, Ferrara, Italy. June 25-27th, 2008
  36. F. Mangolini, A. Rossi, N.D. Spencer, Thermal Reactivity of Oil Additives: a Comparison between Zinc Dialkyldithiophosphate (ZnDTP) and Triphenyl Phosphorothionate (TPPT) (poster presentation), European Conference on Application of Surface and Interface Analysis (ECASIA) 2007, Brussels, Belgium. September 9-14th, 2007
  37. P.L Cavallotti, L. Magagnin, F. Mangolini, Electodeposition of Sacrificial Mn–Cu Alloys on Steel (oral presentation), 1st European Pulse Plating Seminar: From Fundamentals to Industrial Application, Vienna, Austria. March 10th, 2006
  38. F. Mangolini, L. Magagnin, P.L. Cavallotti, Pulse Plating of Sacrificial Mn–Cu Alloys on Steel (poster presentation), NACE’s Annual Meeting, CORROSION/2006 at San Diego Convention Center in San Diego, California, US. March 12-16th, 2006
  39. F. Mangolini, L. Magagnin, P.L. Cavallotti, Electrodeposition of Sacrificial Mn–Cu Alloys on Steel (oral presentation), the 56th Annual Meeting of the International Society of Electrochemistry (ISE), Busan, Korea. September 25-30th, 2005

 

Awards, Scholarships & Fellowships

  • Fall 2013 University of Pennsylvania Research Foundation Award (role: Co-PI). Grant awarded by the University Research Foundation (URF) of the University of Pennsylvania to develop an in situ tribological apparatus to be installed inside an environmental X-ray photoelectron spectrometer
  • Marie Curie International Outgoing Fellowship for Career Development (IOF). This fellowship supports my independent postdoctoral research at the University of Pennsylvania and at Ecole Centrale de Lyon
  • Postdoctoral Fellowship for Prospective Researchers by the Swiss National Science Foundation (SNSF). This fellowship supported my first year of independent postdoctoral research at the University of Pennsylvania
  • Field Best Presentation Award (U36) at the World Tribology Congress 2009, Kyoto, Japan
  • Harvey Herro Award (3rd place) for the Best Poster in Applied Corrosion Technology at NACE International CORROSION/2006, San Diego, California

 

Links

Filippo Mangolini’s Home Page